I am also needing to do the floor of my van , being a car stereo nut i know of a product called DYNAMAT its used to reduce road noise and absorb vibration ,
its like a sheet of aly foil with a black tar like stuff on the back so it sticks to the surface and stays there.
it will not let any road noise thru and because its stuck to the floor it should protect it from rust aswell.
as for the floor, make it in 2 or 3 pieces separated laterally so you can remove them for washing and rust inspection.
the only downside i can see with this is that its quite expensive at about $500 for the back floor of a lwb hiace its also a bit on the heavy side because it is rather dense.
but i guess if it stops the rust then its cheap insurance for your van